PERMATEX INDUSTRIAL CORPORATION
07/02/97
ROCKY HILL,
CONNECTICUT 06067
TELEPHONE:
(860) 571-5100
MATERIAL SAFETY
DATA SHEET Page 01 of 06
Permatex(R) Blue RTV Silicone Gasket Maker
81860
1.
CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: Permatex(R)
Blue RTV Silicone Gasket Maker
Sensor-Safe
Item No.: 81860
Part No.: 6MA
Part Number: 6MA
Product Type: RTV-Silicone
Aerosol
2.
COMPOSITION, INFORMATION ON INGREDIENTS
Ingredients CAS
No. %
SEALANT
Non-hazardous ingredients Proprietary 80-90
Poly(dimethylsiloxane),
hydroxy terminated 70131-67-8 1-10
Ethyltriacetoxysilane
17689-77-9 1-10
Methyltriacetoxysilane
4253-34-3 1-10
SILICA, AMORPHOUS (FUMED) 7631-86-9 1-10
ACETIC ACID
64-19-7 ***
PROPELLANT
BUTANE
106-97-8 5-80
PROPANE
74-98-6 5-80
ISOBUTANE 75-28-5 5-80
***When this product is exposed to moisture, 3-5% acetic acid may be
formed.
Ingredients which have exposure limits
Exposure Limits (TWA)
ACGIH OSHA OTHER
Ingredients
(TLV) (PEL)
SEALANT
SILICA, AMORPHOUS (FUMED) 10mg/m3
TWA 6mg/m3 TWA None
ACETIC ACID 10 ppm
TWA 10 ppm TWA None
25
mg/m3 25 mg/m3
PROPELLANT
PERMATEX INDUSTRIAL CORPORATION
07/02/97
ROCKY HILL,
CONNECTICUT 06067
TELEPHONE:
(860) 571-5100
MATERIAL SAFETY
DATA SHEET Page 02 of
06
Product Name: Permatex(R)
Blue RTV Silicone Gasket Maker
Sensor-Safe
Item No.: 81860
2.
COMPOSITION, INFORMATION ON INGREDIENTS (continued)
BUTANE 800 ppm
TWA 800 ppm TWA None
1900mg/M3 1900mg/M3
PROPANE
Asphyxiant 1000 ppm None
1800 mg/m3
Exposure Limits (STEL) ACGIH OSHA
Ingredients
(TLV) (PEL)
SEALANT
ACETIC ACID 15
ppm None
37
mg/m3
PROPELLANT
3.
HAZARDS IDENTIFICATION
Toxicity: Eye and skin
irritant.
Moderately
toxic by ingestion.
If use creates
respirable particles, some
respiratory
systems injury may occur. May enhance
allergic conditions
in certain people.
Primary Routes of Entry: Skin,
ingestion, inhalation, eyes.
Signs and symptoms
of Exposure: Acetic acid produced during cure
irritates eyes,
nose throat.
May cause moderate corneal injury and
considerable
redness to eyes.
Inhalation may
may cause difficulty in breathing.
Ingestion may
cause vomiting. Swallowing large
amounts may
cause digestive discomfort.
Existing Conditions
Aggravated by Exposure: Heart disease and respiratory
disorders.
Methyltriacetoxysilane: Eye, skin, and pulmonary
disorders.
Literature
Referenced Carcinogen
Ingredients Target Organ and
Other Health Effects NTP IARC
OSHA
SEALANT
Non-hazardous ingredients No
Data NO NO
NO
Poly(dimethylsiloxane),
hydroxy terminated No Data NO NO NO
Ethyltriacetoxysilane No
Data NO NO
NO
Methyltriacetoxysilane No
Data NO NO
NO
PERMATEX INDUSTRIAL CORPORATION 07/02/97
ROCKY HILL,
CONNECTICUT 06067
TELEPHONE:
(860) 571-5100
MATERIAL SAFETY
DATA SHEET Page 03 of
06
Product Name: Permatex(R)
Blue RTV Silicone Gasket Maker
Sensor-Safe
Item No.: 81860
3.
HAZARDS IDENTIFICATION
(continued)
SILICA, AMORPHOUS (FUMED) NUI NO
N/A NO
ACETIC ACID COR EYE
GAS IMM IRR NO NO
NO
PROPELLANT
BUTANE CAR CNS
IRR NO NO
NO
PROPANE CAR CNS
IRR NO NO NO
ISOBUTANE CAR CNS
LUN NO NO
NO
-------------------------------------------------------------------------------
Abbreviations
N/A Not Applicable
CAR Cardiac
CNS Central nervous system COR Corrosive
EYE Eyes
GAS Gastrointestinal
IMM Immune system
IRR Irritant
LUN Lung
NUI Nuisance dust
4.
FIRST AID MEASURES
Ingestion: Do not induce
vomiting. Keep individual calm.
Obtain medical
attention.
Inhalation: Remove to
fresh air. Treat symptomatically.
Skin Contact: Wipe off paste
with paper towel or cloth. Wash
exposed area with soap and water.
Eye Contact: Flush at least
15 minutes with water. Obtain
medical
attention.
5.
FIRE FIGHTING MEASURES
Flash Point: 212°F (Base
only) Method: Tag closed cup
Recommended
Extinguishing Agents: Carbon dioxide, water fog, dry
chemical
Hazardous Products formed
by Fire or Thermal Decomp Acetic acid,
formaldehyde, silica fume, carbon
dioxide
Unusual Fire or
Explosion Hazards:
Containers may vent, rupture, or burst at elevated
temperatures.
Explosive Limits:
(% by volume in air)Lower 1.8%
(% by volume in air)Upper 9.5%
PERMATEX INDUSTRIAL CORPORATION 07/02/97
ROCKY HILL,
CONNECTICUT 06067
TELEPHONE:
(860) 571-5100
MATERIAL SAFETY
DATA SHEET Page 04 of
06
Product Name: Permatex(R)
Blue RTV Silicone Gasket Maker
Sensor-Safe
Item No.: 81860
6.
ACCIDENTAL RELEASE MEASURES
Steps to be taken in case
of spill or leak: Wipe and/or scrape up spilled
material. Maintain
good ventilation for large spills. Place scrap
material in a
well-ventilated place and allow to
cure to
rubber.
7.
HANDLING AND STORAGE
Safe Storage: Store away
from heat, spark or open flame.
Store below
120°F.
(Contact Loctite Customer Service
1-800-243-4874 for shelf Life information)
Handling: Avoid
prolonged breathing of vapor. Keep
away
from eyes.
Avoid prolonged skin contact.
Keep away from
heat, sparks, or open flame.
Do not smoke
while using. Wash hands after use.
When spraying
more than one half can or more than
one can consecutively, use
NIOSH/MSA approved
respirator.
8.
EXPOSURE CONTROLS, PERSONAL PROTECTION
Eyes: Safety glasses
or goggles.
Skin: Rubber or
plastic gloves. Long sleeves and long
pants.
Ventilation: Provide
adequate local ventilation to maintain
vapor
concentration below TLV.
Use self
contained breathing apparatus when vapor
concentration
exceeds TLV.
See Section 2
for Exposure Limits.
9.
PHYSICAL AND CHEMICAL PROPERTIES
The properties listed below apply to the base material only.
Appearance: Blue paste
Odor: Acetic
acid
Boiling Point: None:
Polymeric Material
pH: Does not
apply
Solubility in Water: Nil
Specific Gravity 1.04
Volatile Organic Compound
(EPA Method 24) 9.6% ; 100 grams per liter (calculated)
Vapor Pressure: 66 psig
Vapor Density: More than
1
PERMATEX INDUSTRIAL CORPORATION
07/02/97
ROCKY HILL,
CONNECTICUT 06067
TELEPHONE:
(860) 571-5100
MATERIAL SAFETY
DATA SHEET Page 05 of
06
Product Name: Permatex(R)
Blue RTV Silicone Gasket Maker
Sensor-Safe
Item No.: 81860
9.
PHYSICAL AND CHEMICAL PROPERTIES
(continued)
Evaporation Rate
(Ether = 1) Slower than butyl acetate
10. STABILITY AND REACTIVITY
Stability: Stable
Hazardous Polymerization: Will not occur
Incompatibility: Strong
acids.
Adhesive is
polymerized by contact with moisture.
Conditions to Avoid: Not
available
Hazardous Decomposition
Products (non-thermal): Acetic acid fumes.
11. TOXICOLOGICAL INFORMATION
See Section
3.
12. ECOLOGICAL INFORMATION
No data
available
13. DISPOSAL CONSIDERATIONS
Recommended methods of
disposal: Cured rubber scrap can be
incinerated. Follow EPA
local
regulations for disposal of aerosol cans.
EPA Hazardous Waste
Number D001 - Hazardous waste per
40CFR 261.21
14. TRANSPORTATION INFORMATION
DOT (49 CFR 172)
Domestic Ground Transport
Proper Shipping Name: Consumer Commodity
Hazard Class or
Division: ORM-D
Identification Number: None
Marine Pollutant: None
IATA
Proper Shipping Name: Consumer Commodity (Not more than 500
ml);
Aerosols, flammable
n.o.s. (More than 500 ml)
Class or Division: Class 9 (Not more than 500 ml);
Division 2.1
(More than 500 ml)
UN or ID Number: ID 8000 (Not more than 500 ml);
UN 1950 (More than 500 ml)
PERMATEX INDUSTRIAL CORPORATION
07/02/97
ROCKY HILL,
CONNECTICUT 06067
TELEPHONE:
(860) 571-5100
MATERIAL SAFETY DATA SHEET Page 06 of 06
Product Name: Permatex(R)
Blue RTV Silicone Gasket Maker
Sensor-Safe
Item No.: 81860
15. REGULATORY INFORMATION
CA Proposition 65: No Prop65
chemicals are known to be present.
16. OTHER INFORMATION
Estimated NFPA(R) Code:
Health Hazard: 1
Fire Hazard: Sealant: 1; Propellant: 4
Reactivity Hazard: 0
Specific Hazard: Does not apply
Estimated HMIS(R) Code:
Health Hazard: 1
Flammability Hazard: Sealant: 1; Propellant: 4
Reactivity Hazards: 0
Personal Protection: See Section 8.
NFPA is a registered trademark of the National Fire Protection
Assn.
HMIS is a registered trademark of the National Paint and Coatings
Assn.
Prepared By: Stephen
Repetto
Title: Research
Chemist, Health and Safety
Company: Loctite Corp.,
1001 Tr Br Cr, Rocky Hill CT 06067
(24hr.) Phone: (860)
571-5100
Revision Date: January 22,
1996 Revision: 0005